http://SaturnianCosmology.Org/ mirrored file For complete access to all the files of this collection see http://SaturnianCosmology.org/search.php ========================================================== Geology; April 2010; v. 38; no. 4; p. 355-358; DOI: 10.1130/G30508.1 © 2010 Geological Society of America Cometary airbursts and atmospheric chemistry: Tunguska and a candidate Younger Dryas event Adrian L. Melott^1, Brian C. Thomas^2, Gisela Dreschhoff^1 and Carey K. Johnson^3 ^1 Department of Physics and Astronomy, University of Kansas, Lawrence, Kansas 66045, USA ^2 Department of Physics and Astronomy, Washburn University, Topeka, Kansas 66621, USA ^3 Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA We find agreement between models of atmospheric chemistry changes^ from ionization for the A.D. 1908 Tunguska (Siberia region,^ Russia) airburst event and nitrate enhancement in Greenland^ Ice Sheet Project 2 (GISP2H and GISP2) ice cores, plus an unexplained^ ammonium spike. We then consider a candidate cometary impact^ at the Younger Dryas onset (YD). The large estimated NO[x] production^ and O[3] depletion are beyond accurate extrapolation, but the^ ice core peak is much lower, possibly because of insufficient^ sampling resolution. Ammonium and nitrate spikes in both Greenland^ Ice Core Project (GRIP) and GISP2 ice cores have been attributed^ to biomass burning at the onset of the YD. A similar result^ is well resolved in Tunguska ice core data, but that forest^ fire was far too small to account for this. Direct input of^ ammonia from a comet into the atmosphere is adequate for YD^ ice core data, but not for the Tunguska data. An analog of the^Haber process with hydrogen contributed by cometary or surface^ water, atmospheric nitrogen, high pressures, and possibly catalytic^ iron from a comet could in principle produce ammonia, accounting^ for the peaks in both data sets.^